Análise potenciométrica de redissolução com ultramicroeletrodos: fundamentos e aplicações na determinação de metais traços. Quím. Nova [online]. 09/02/ la química analítica es la parte de la química que estudia, diseña, desarrolla, optimiza y aplica métodos y técnicas que se materializan en. fundamentos fisioquímicos grado farmacia us métodos químicos: son todos aquellos que se basan casi exclusivamente en reacciones químicas en los que la.

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New York,vol. However, it should be pointed out that only at constant ionic strength a linearrelationship between the signal measured and the concentration of the analyte is maintained because of the clear cut relationship between ion activity and concentration, occurring in such condition.

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However, a membrane truly selective for a single typeof an ion and completely non-selective for other ions does not exist. The linear range of the calibration curve is usually applied to determine the activity of the target ionin potenciometra unknown solution.

The selectivity coefficient Kxy has been introducedin the Nikolski-Eisenman equation. A useful slope can be regarded as [mV per decade] [mV per decade] for double charged ion respectively.

[Potencio & Conduto] Aula – Métodos Eletroquímicos e Titulação Potenciométrica (Guts)

Industrial Processing of Cotton-Seed apud ref. Positive values of log Kxy indicate the preference of an electrode for theinterfering ion. New York,cap. It is important to note that this is a measurement at zero current i.

This membrane can be prepared as: At high and very low target ion activities there are deviations from linearity. Negative values indicate a preference for the target ion relative to the interfering ion.

It establishes the preference with which the sensor responds to the analyte in the presence of various interfering ions from the sample. Most often it is expressed as the logarithm of Kxy. Moreover, in many investigationsthe response time of the overall measuring system is determined, which influences on the response time of the ISE. If ions can penetrate the boundary betweentwo phases, then an electrochemical equilibrium will be reached, fundammentos which different potentials in the fundamentps phases are formed.


This definition can be extended to consider the drift of the system. Typically, the electrode calibration curve exhibits linear response range between M and M.

How to cite this article. Free fatty acids are a measure of evaluating fats and oils, submitted to potsnciometria conditions, besides being a quality characteristic of edible vegetable oils.

If only one type of an ion can be exchanged between the two phases, then the potential difference formed between the phases is governed only by theactivities of this target ion in these phases. For potenciometrja and degummed oils, the titration end point is difficult to be observed due to the high level of pigments, resulting in dark solutions.

According the Fundamento recommendation the detection limit is defined by the cross-sectionof the two extrapolated linear parts od the ion-selective calibration curve. The influence of the presence fundamenots interfering species in a sample solution on themeasured potential difference is taken into consideration in the Nikolski-Eisenman formalism: The measured signal is the sum of different potentials generated at all solid-solid, solid-liquid and liquid-liquid interfaces.

Equilibrium means that the transfer of ions from the membrane into solution is equal to the transfer from the solution to the membrane.

Potentiometric titration applied to free fatty acid determination of edible oils and fats. In practice the potential difference i. If potenciometia example metal buffers are used to eliminate the effectswhich lead to the contamination of very dilute solutions it is possible to enhance the pogenciometria limit down to M. Dois tipos de erros podem ter ocorrido: An examplary set-up for the measurement of electromotive force is precented in figure 1. The theoretical valueaccording to the Nernst equation is: Different methods of the selectivity determination can be found in the literature.


The experimental selectivity coefficients depend on the activity and a method of their determination.

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Eletrodos Ion-Seletivos The potential difference can be measured between two identical reference electrodes placed in the two phases. The selectivity is one of the most important characteristics of an electrode, as it oftendetermines whether a reliable measurement in the sample is possible or not.

Typically such a membrane contains an analyte-selective component whichis responsible for the recognition process. Nova17 In practice, detection limit on the order of M is measured for most of ion-selective electrodes.

There is also an alternative method of the selectivity determination called matchedpotential method MPM. Europa’s Quality Acceptance apud ref. An ion-selective membrane is the key component of all potentiometric ion sensors. According to the nature of the binding sites, the membranes can be classified as: The observed detection limit is often governedby the presence of other interfering ions fundamentox impurities.

The official method of determination AOCS Ca 5a, is based on titration, using phenolphthalein as an indicator. Release 10 for WindowsMinitab: However, in certain applications the value of the electrode slope is not criticaland worse value does not exclude its usefulness. For this reason the potential of sucha membrane is governed mainly by the activity of the primary target ion and also by the activity of othersecondary interfering ions.

Eletrodos Ion-Seletivos When the membrane separates two solutions of different ionic activities a1 and a2 and provided the membrane is ufndamentos permeable to this single type of ion, the potential difference E across the membrane is described by the Nernst equation: In this case and others, such as self-life studies, in which sample quantities are limited, potentiometric titration may be a very good alternative.